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The Group's aim is to identify, survey, protect and promote geological and geomorphological sites in the former County of Avon - the modern unitary authorities of Bath and North East Somerset, Bristol, North Somerset and South Gloucestershire. RIGS are selected for their educational, research, historical and aesthetic value.

Monday 18 February 2013

Baryte (BaSO4)

Minerals of the Avon region
Baryte   (Barium Sulphate – BaSO4)


Colour: White but is often coloured by other minerals to a pink or pale brown

Polymorphism: Forms a series with Selestine

Name: From the Greek for weight due to it’s high specific gravity      

Crystal system: Orthorhombic with up to 70 forms

Specific gravity: 4.5 measured (4.47 calculated)
                           
Hardness: 2.5 – 3.5

Group: Barite Group

Association: Fluorite, calcite, dolomite, rhodochrosite, gypsum,                        sphalerite, galena, stibnite.

Occurrence: A gangue mineral in low-temperature                                         hydrothermal veins; in residual deposits from weathered barite-bearing limestones.

Local location: Stancombe Quarry, Flax Bourton (Working limestone quarry)

Cross section of Baryte vein -Stancombe Quarry
Picture credits Richard Kefford
Larger pictures can be seen here

Paragenesis #1 - Bilbao supergene type
During the Late Triassic, iron rich saline oxidising water leached through the rift basins formed during the early Permian (~290 Ma) to the late Jurassic (~150 Ma).


Paragenesis #2 - Mississippi Valley Type ( MVT )
In the Mendip – Bristol vein field, baryte has been deposited by hydrothermal fluids in tension cracks and fissures in the Carboniferous Limestone. The primary minerals in these fissures are Galena and Sphalerite. Gangue minerals such as Baryte and Calcite occur in banded formations where the veins pinch out. This is known as the Mississippi Valley Type (MVT) and took place during the Middle Jurassic (~170Ma).


Baryte with associated galena and calcite - Stancombe Quarry


Uses:
By far the greatest use of this mineral ~80%, is for the production of drilling mud for use in oil exploration. The main reason for this is that it is very heavy and so helps to prevent blow outs in the drilling stage of the exploitation of an oil reservoir. It is also chemically inert. The specification for drilling mud includes a requirement that the specific gravity should be 4.2 or greater.

Non drilling applications of barytes are comparatively small, although still important because of their higher value. High purity grades of barytes with fine and controlled particles sizes are used as fillers in marine and industrial paints, in brake lining/ friction materials and in plastics. A specialised use of barytes based on its high density and ability to absorb radiation, is as an aggregate in dense concrete for shielding applications in the nuclear industry and hospital radiation departments.


Bladed rosettes of Baryte on associated red ochre
Sample found by Leon Sparrow at Winford

Sources:
Barytes is produced in England and Scotland. In England it is now only produced as a by product of fluorspar mining and processing. In Scotland, barytes is extracted as the sole mineral from the Foss Mine near Aberfeldy. 



Richard Kefford

References:



Chidlaw, N. (2012) Metamorphism and Mineralisation in the Bristol - Mendip area

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